CODE EXAMPLE FOR PYTHON

python sort_values

df.sort_values(by='col4', key=lambda col: col.str.lower())
   col1  col2  col3 col4
0    A     2     0    a
1    A     1     1    B
2    B     9     9    c
3  NaN     8     4    D
4    D     7     2    e
5    C     4     3    F