import numpy as np
import pandas as pd
a = [['10', '1.2', '4.2'], ['15', '70', '0.03'], ['8', '5', '0']]
df = pd.DataFrame(a, columns=['one', 'two', 'three'])
df['que'] = np.where((df['one'] >= df['two']) & (df['one'] <= df['three'])
, df['one'], np.nan)