In [2]: df Out[2]: A B 0 p1 1 1 p1 2 2 p3 3 3 p2 4 In [3]: df.loc[df['B'] == 3, 'A'] Out[3]: 2 p3 Name: A, dtype: object In [4]: df.loc[df['B'] == 3, 'A'].iloc[0] Out[4]: 'p3'