print(df)
col1 col2 col3
0 1 11 111
1 2 22 222
2 3 33 333
s = df.pop('col1')
new_df = pd.concat([df, s], 1)
print(new_df)
Output:
col2 col3 col1
0 11 111 1
1 22 222 2
2 33 333 3
cols = [df.columns[-1]] + [col for col in df if col != df.columns[-1]]
df = df[cols]